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  • th3m0ment's Avatar
    137 posts since Oct '03
  • poon cho tang's Avatar
    127,607 posts since Sep '04
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    ^tamago^'s Avatar
    51,105 posts since Sep '03
  • th3m0ment's Avatar
    137 posts since Oct '03
  • dbowie's Avatar
    4,041 posts since Mar '07
    • eh..
      aquerous means in water..
      (l) also means in water..
      except u always put H2O as (l)..

  • poon cho tang's Avatar
    127,607 posts since Sep '04
    • pedantically,

      (l) could be more to indicate that water, as a participating reagent, is in its liquid state

      (aq) has a double meaning, inferring that water is reacting both in its liquid state and "dissolved" as H+ and O2- ions

      Laughing

  • starmoonsun's Avatar
    64 posts since Jul '07
    • huh???
      i thought (l) is because it is like distilled water, no ions disassociate
      then aqueous will have
      -confused-

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    ^tamago^'s Avatar
    51,105 posts since Sep '03
    • er, if you are O level, just take H20 as (l) can liao.
      for A level it gets a bit more complicated.

  • tanjun's Avatar
    1,057 posts since Jan '05
    • For me, I will put the state symbol of H2O as l. The state symbol (aq) refers to a solution that is dissolved in water. It makes no sense to say that H2O dissolves in H2O.

      For example: HCL (aq) refers to hydrochloric acid while HCL (g) refers to hydrogen chloride gas. Hydrochloric acid is a product when hydrogen chloride is pumped and dissolved in water.

      Hydrochloric acid has acidic properties while hydrogen chloride gas doesn't.

      Thus, my stand on H2O(l) result.

  • rain-coat's Avatar
    492 posts since Sep '07
    • H2O is (l) since its in the liquid form, just like eg. NaCl(l) in molten state. (aq) is for substances dissolved in water eg. NaCl(aq) sodium chloride solution.

  • ultranova3's Avatar
    128 posts since Aug '07
    • Originally posted by poon cho tang:
      pedantically,

      (l) could be more to indicate that water, as a participating reagent, is in its liquid state

      (aq) has a double meaning, inferring that water is reacting both in its liquid state and "dissolved" as H+ and O2- ions

      Laughing

      O2-??
      I thought it is OH-.
      2H2O H3O+ + OH-
      How do we get oxide ion?
      O2- + H2O 2OH- ??? Question Shocked

  • sirron kcuhc's Avatar
    276 posts since Oct '07
  • unclebutcher's Avatar
    2,819 posts since Oct '06
    • Originally posted by th3m0ment:
      anyone can explain the difference between H2O(l) and H2O(aq)? aren't they the same?

      for o levels, no such thing as H2O (aq). aq means the compund has dissociated in a solvent, which is illogical for h2o as h2o cannot dissociate in h2o. Wink

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    Darkness_hacker99's Avatar
    31,746 posts since Jun '05
    • Originally posted by unclebutcher:
      for o levels, no such thing as H2O (aq). aq means the compund has dissociated in a solvent, which is illogical for h2o as h2o cannot dissociate in h2o. Wink

      How about A Level?

      I don't mind to learn more Smile

  • ultranova3's Avatar
    128 posts since Aug '07
    • I think the term should be auto-protonation of water/self-ionization of water/auto-dissociation of water.

      2H2O(l) H3O+(aq) + OH-(aq) Kw = 1 x 10^-14
      Kw is water dissociation constant. You can find more about this in acid-base equilibria.

      Laughing Laughing Laughing Rolling Eyes Rolling Eyes Rolling Eyes

  • HyuugaNeji's Avatar
    1,648 posts since Jun '05
    • When they put H2O(l), it usually mean the water does not take part in the chemical reaction.

      Bluff you la.

      Water(l) is put in there to confuse pple. Laughing

      Edited by HyuugaNeji 21 Oct `07, 1:16AM
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    Darkness_hacker99's Avatar
    31,746 posts since Jun '05
    • Originally posted by HyuugaNeji:
      When they put H2O(l), it usually mean the water does not take part in the chemical reaction.

      Bluff you la.

      Water(l) is put in there to confuse pple. Laughing

      But But But...

      Say Alkali metal react with water.

      K(s) + H2O(l) --> KOH(aq) + H2(g)

      So water take part in the chemical reaction right? Laughing

  • HyuugaNeji's Avatar
    1,648 posts since Jun '05
    • Originally posted by Darkness_hacker99:
      But But But...

      Say Alkali metal react with water.

      K(s) + H2O(l) --> KOH(aq) + H2(g)

      So water take part in the chemical reaction right? Laughing

      I say usually ma. Not always.

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    Darkness_hacker99's Avatar
    31,746 posts since Jun '05
  • dbowie's Avatar
    4,041 posts since Mar '07
  • ultranova3's Avatar
    128 posts since Aug '07
    • Originally posted by Darkness_hacker99:
      But But But...

      Say Alkali metal react with water.

      K(s) + H2O(l) --> KOH(aq) + H2(g)

      So water take part in the chemical reaction right? Laughing

      If you want, explain it using equilibria. For simplicity, I will use H+ instead of H3O+.

      H2O H+ + OH- Reaction 1 (equilibrium reaction)
      2K(s) + 2H+(aq) --> 2K+(aq) + H2(g). reaction 2 (forward reaction)
      This reaction will always go forward.
      Since H+ is being consumed in reaction 2, concentration of H+ will decrease. As such, by Le Chartelier's Principle, the system will try to produce more H+ in reaction 1 so that the system reaches the equilibrium, by shifting the equilibrium of reaction forward (to the right) favouring production of H+ and OH-.

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