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The solubility of a given solute in a given solvent typically depends on temperature. For around 95% of solid solutes, the solubility increases with temperature, in the temperature range from about ambient to 100 °C.
http://en.wikipedia.org/wiki/Solubility#Temperature
Thus decreasing temperature of the solvent decreases its solubility, thus crystals start to form?
I dunno how to explain in molecular perspective.
Edited by secretliker 15 Apr `08, 5:51PM
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